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High dielectric permittivity and low dielectric loss nanocomposites based on poly(VDF-TrFE-CTFE)and graphene nanosheets

基于聚(VDF-三氟乙烯-CTFE)和石墨烯纳米片的高介电常数和低介电损耗的纳米复合材料

作     者:Fei Wen Zhuo Xu Weimin Xia Xiaoyong Wei Zhicheng Zhang 

作者机构:Electronic Materials Research LaboratoryKey Laboratory of the Ministry of Education&International Center for Dielectric ResearchXi’an Jiaotong UniversityXi’an 710049P.R.China Department of Applied ChemistryMOE Key Laboratory for Nonequilibrium Synthesis and Modulation of Condensed MatterSchool of ScienceXi’an Jiaotong UniversityXi’an710049P.R.China 

出 版 物:《Journal of Advanced Dielectrics》 (先进电介质学报(英文))

年 卷 期:2013年第3卷第2期

页      面:33-38页

学科分类:08[工学] 0805[工学-材料科学与工程(可授工学、理学学位)] 080502[工学-材料学] 0702[理学-物理学] 

基  金:support from the National Basic Research Program of China(973 Program)(Grant No.2009CB623306) International Science&Technology Cooperation Program of China(Grant No.2010DFR50480) National Nature Science Foundation of China-NSAF(Grant Nos.10976022,50872107 and 50903065) Program for NewCentury Excellent Talents in University, and FundamentalResearch Funds for the Central Universities 

主  题:Dielectric graphene nanosheets nanocomposites ferroelectric elastomer 

摘      要:In this work,nanocomposites(poly(vinylidenefluoridetrifluoroethylenechlorotrifluoroethylene)/Graphene nanosheets)(P(VDF-TrFE-CTFE)/GNS)were fabricated via solution cast *** were covalently functionalized with KH550 to improve their interfacial interactions with the terpolymer matrix P(VDF-TrFE-CTFE).Compared to neat terpolymer,significantly improved dielectric permittivity and low loss were observed for the *** instance,at 1 kHz the P(VDF-TrFE-CTFE)/GNS composites with 4%GNS possessed a dielectric permittivity of 144,over 14 times larger than that of neat terpolymer,while the loss was only *** findings represent an effective route to design potential dielectric polymer films for high-charge storage capacitors.

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