High dielectric permittivity and low dielectric loss nanocomposites based on poly(VDF-TrFE-CTFE)and graphene nanosheets
基于聚(VDF-三氟乙烯-CTFE)和石墨烯纳米片的高介电常数和低介电损耗的纳米复合材料作者机构:Electronic Materials Research LaboratoryKey Laboratory of the Ministry of Education&International Center for Dielectric ResearchXi’an Jiaotong UniversityXi’an 710049P.R.China Department of Applied ChemistryMOE Key Laboratory for Nonequilibrium Synthesis and Modulation of Condensed MatterSchool of ScienceXi’an Jiaotong UniversityXi’an710049P.R.China
出 版 物:《Journal of Advanced Dielectrics》 (先进电介质学报(英文))
年 卷 期:2013年第3卷第2期
页 面:33-38页
学科分类:08[工学] 0805[工学-材料科学与工程(可授工学、理学学位)] 080502[工学-材料学] 0702[理学-物理学]
基 金:support from the National Basic Research Program of China(973 Program)(Grant No.2009CB623306) International Science&Technology Cooperation Program of China(Grant No.2010DFR50480) National Nature Science Foundation of China-NSAF(Grant Nos.10976022,50872107 and 50903065) Program for NewCentury Excellent Talents in University, and FundamentalResearch Funds for the Central Universities
主 题:Dielectric graphene nanosheets nanocomposites ferroelectric elastomer
摘 要:In this work,nanocomposites(poly(vinylidenefluoridetrifluoroethylenechlorotrifluoroethylene)/Graphene nanosheets)(P(VDF-TrFE-CTFE)/GNS)were fabricated via solution cast *** were covalently functionalized with KH550 to improve their interfacial interactions with the terpolymer matrix P(VDF-TrFE-CTFE).Compared to neat terpolymer,significantly improved dielectric permittivity and low loss were observed for the *** instance,at 1 kHz the P(VDF-TrFE-CTFE)/GNS composites with 4%GNS possessed a dielectric permittivity of 144,over 14 times larger than that of neat terpolymer,while the loss was only *** findings represent an effective route to design potential dielectric polymer films for high-charge storage capacitors.