Comparative cyclic oxidation behaviour and effect of oxides on hardness of wear resistance coating alloys T-401 and T-900
作者机构:Key Laboratory of Advanced MaterialsMinistry of EducationSchool of Materials Science and EngineeringCollaborative Innovation Center of Advanced Nuclear Energy TechnologyTsinghua UniversityBeijing 100084China
出 版 物:《Journal of Iron and Steel Research International》 (国际钢铁研究杂志)
年 卷 期:2019年第26卷第10期
页 面:1069-1079页
核心收录:
学科分类:08[工学] 080502[工学-材料学] 0805[工学-材料科学与工程(可授工学、理学学位)]
主 题:Tribaloy Hypoeutectic alloy Hypereutectic alloy Cyclic oxidation Depletion Nitride Hardness
摘 要:The investigated alloys are newly developed Tribaloy alloys with enhanced crack and oxidation resistance over the traditional Tribaloy *** cyclic oxidation performance and effects of complex oxides on the hardness of cobaltbased Tribaloy alloys T-401(hypoeutectic)and T-900(hypereutectic)were *** results showed that T-900 alloy has a lower oxidation rate as compared to T-401 alloy at 800 and 1000℃,which attributed to the formation of dense continuous Cr2O3 layer with an upper thinner continuous layer of CoCr2O4 and NiCr2O4 *** 1000℃,T-401 alloy exhibited poor oxidation resistance due to severe spallation after 3 cycles(45 h).After oxidation,T-900 alloy exhibits 98%and 18%lower mass gain than T-401 alloy at 1000 and 800℃,*** T-900 alloy,relationship between mass gain and thickness of oxide layer revealed that mass will increase 0.162 mg/cm2 for every 1-μm increase in the oxides *** SiO2 oxide was observed at 800 and 1000℃for both ***,the extent of internal Si oxides increased with increasing oxidation temperature from 800 to 1000℃.Consequently,internal oxidation of Si led to the formation of Laves phase-depleted region near oxide/alloy interface in T-900 alloy at 1000℃.Thus,hardness of T-900 alloy decreased from 618 to 392 HV beneath the oxide/alloy interface at 1000℃,whereas hardness of T-900 and T-401 alloys after cyclic oxidation test at 800℃increased from 618 to 855 and 519 to 685 HV,respectively.