High coercivity Nd-Ce-Fe-B nanostructured ribbons prepared from melt spinning technique
High coercivity Nd-Ce-Fe-B nanostructured ribbons prepared from melt spinning technique作者机构:State Key Laboratory for Mesoscopic PhysicsSchool of PhysicsPeking UniversityBeijing100871China Institute of International EconomyUniversity of International Business and EconomicsBeijing100029China Functional Materials Research Institut5Central Iron&Steel Research Institut5Beijing100081China Robotics Research GroupCollege of EngineeringPeking UniversityBeijing100871China Collaborative Innovation Center of Quantum MatterBeijing100871China Beijing Key Laboratory for Magnetoelectric Materials and DevicesBeijing100871China
出 版 物:《Journal of Rare Earths》 (稀土学报(英文版))
年 卷 期:2019年第37卷第10期
页 面:1053-1058页
核心收录:
学科分类:07[理学] 070205[理学-凝聚态物理] 08[工学] 080501[工学-材料物理与化学] 080502[工学-材料学] 0805[工学-材料科学与工程(可授工学、理学学位)] 0702[理学-物理学]
基 金:Project supported by the National Key Research and Development Program of China(2016YFB0700901) National Natural Science Foundation of China(51731001,11675006,51371009)
主 题:Nd-Fe-B alloy Ce substitution Coercivity Rare earths
摘 要:The Ce-substituted(Nd1-xCex)12.2 Fe81.6 B6.2(x=0.0, 0.2, 0.4, 0.6) nanocrystalline ribbons were prepared by annealing amorphous ribbons from melt spinning. It is found that all ribbons are in a multiphase state consisting of a-Fe phase, Nd(Ce)-rich phases and RE2 Fe14 B(RE = Nd, Ce) phases. However, the coercivity of all annealed ribbons can reach a considerably high value without doping any heavy rare earth or other coercivity enhanced elements. A strong intergranular exchange coupling appears in these nanocrystalline ribbons. The Nd12.2 Fe81.6 B6.2 ribbons with multiphase have a coercivity of about 11.3 k Oe, and the coercivity decreases slightly with increasing Ce content. A coercivity of 7.5 kOe can be obtained when60 at% of Nd is replaced by Ce(x = 0.6) due to the grain refinement and the strong intergranular exchange coupling. This provides a practical approach of fabricating high coercivity Ce-substituted Nd-Fe-B materials.