磷掺杂TiO2薄膜的制备与表征及其可见光照射下光催化降解邻苯二甲酸丁苄酯性能(英文)

作     者：R.M.MOHAMED E.AAZAM R.M.MOHAMED;E.AAZAM

作者机构：Chemistry DepartmentFaculty of ScienceKing Abdulaziz UniversityP.O. Box: 80203Jeddah 21589Saudi Arabia Advanced Materials DepartmentCentral Metallurgical R&D InstituteCMRDIP.O. Box 87HelwanCairoEgypt 

出 版 物：《催化学报》 (Cuihua Xuebao Chin. J. Catalysis)

年 卷 期：2013年第34卷第6期

页      面：1267-1273页

核心收录：

学科分类：083002[工学-环境工程] 0830[工学-环境科学与工程（可授工学、理学、农学学位）] 081705[工学-工业催化] 08[工学] 0817[工学-化学工程与技术] 

主　　题：Phosphorus‐doped Titania Thin film Visible light Photocatalyst 

摘      要：P‐doped TiO2 (PTIO) thin‐films with different P contents were prepared using a sol‐gel method. The thin‐film samples were characterized using various techniques. The photocatalytic activity was evaluated by decomposing butyl benzyl phthalate under visible‐light irradiation. The results showed that the transformation of anatase to the rutile phase was inhibited and grain growth of TiO2 was prevented by P doping. The results confirm that the doped P atoms existed in two chemical forms, and those incorporated in the TiO2 lattice may play a positive role in photocatalysis. The high photocatalytic activities of the PTIO thin‐films may be the result of extrinsic absorption through the creation of oxygen vacancies, rather than excitation of the intrinsic absorption band of bulk TiO2 . The PTIO can be recycled with little depression of the photocatalytic activity. After six cycles, the photocatalytic activity of the PTIO film was still higher than 98%.