Effect of Dodecylbenzene Sulfonic Acid Used as Additive on Residue Hydrotreating

作     者：Sun Yudong Yang Chaohe 

作者机构：College of Chemical Engineering China University of PetroleumQingdao 

出 版 物：《China Petroleum Processing & Petrochemical Technology》 (中国炼油与石油化工（英文版）)

年 卷 期：2015年第17卷第1期

页      面：82-88页

核心收录：

学科分类：081702[工学-化学工艺] 08[工学] 0817[工学-化学工程与技术] 

基　　金：the financial support provided by the National Natural Science Foundation of China (Grant No. 21376266) the Petro China Innovation Foundation (Grant No. 2011D-5006-0405) the Fundamental Research Funds for the Central Universities (Grant No. 27R1104049A) 

主　　题：residue hydrotreating dodecylbenzene sulfonic acid product distribution catalyst properties asphaltenes structure 

摘      要：The effect of additive—dodecylbenzene sulfonic acid(DBSA)—on residue hydrotreating was studied in the au toclave. The results showed that the additive improved stabilization of the colloid system of residue, which could delay th aggregation and coke formation from asphaltenes on the catalyst, and make heavy components transformed into light oi The residue conversion in the presence of this additive increased by 1.94%, and the yield of light oil increased by 1.53%when the reaction time was 90 min. The surface properties of the catalyst in the presence of this additive were better tha that of the blank test within a very short time(30 min) and deteriorated rapidly after a longer reaction time due to highe conversion and coke deposition. Compared with the blank test, the case using the said additive had shown that the structur of hydrotreated asphaltene units was smaller and the condensation degrees were higher. The test results indicated that th additive could improve the hydrotreating reactivity of residue via permeation and depolymerization, the heavier componen could be transformed into light oil more easily, and the light oil yield and residue conversion were higher for the case usin the said additive in residue hydrotreating process.