Solvent extraction of V(Ⅴ) and Cr(Ⅲ) from acidic leach liquors of ilmenite using Aliquat 336

作     者：A.A.NAYL H.F.ALY A.A.NAYL;H.F.ALY

作者机构：Chemistry Department College of Science Aljouf University Hot Laboratories Centre Atomic Energy Authority 

出 版 物：《Transactions of Nonferrous Metals Society of China》 (中国有色金属学报（英文版）)

年 卷 期：2015年第25卷第12期

页      面：4183-4191页

核心收录：

学科分类：080602[工学-钢铁冶金] 080603[工学-有色金属冶金] 08[工学] 0806[工学-冶金工程] 

主　　题：extraction acidic leach liquor Aliquat 336 V(V) Cr(III) 

摘      要：Extraction of V（V） and Cr（III） from acidic sulfate leach liquors of ilmenite using 0.4 mol/L Aliquat 336 chloride in kerosene was carried out. Different parameters affecting the extraction process such as equilibrium time, sulfate concentration, Aliquat 336 concentration, equilibrium p H and the extraction temperature were investigated. Extraction of V（V） and Cr（III） by Aliquat 336 involved anion exchange mechanism, and the extracted species are [（VO2SO4）R4N]org at low equilibrium p H for V（V） and [R4N-Cr（OH）4]org at high equilibrium p H for Cr（III）. Calculated thermodynamic parameters show that the extraction process is endothermic reaction for V（V） and exothermic for Cr（III）. Also, calculated values of ？Gex and ？Sex indicate that the extraction reactions of V（V） and Cr（III） proceed as non-spontaneous reaction is more random. V（V） and Cr（III） were stripped, precipitated, separated and calcined at 500 °C for 2.0 h to produce the corresponding oxide in pure form after rinsing and drying.