Aqueous Solution Preparation of Ruthenium Nanoparticles Using Ammonium Formate as the Reducing Agent

作     者：LIU Shaohong CHEN Jialin GUAN Weiming BI Jun CHEN Nanguang CHEN Dengquan LIU Manmen SUN Xudong LIU Shaohong;CHEN Jialin;GUAN Weiming;BI Jun;CHEN Nanguang;CHEN Dengquan;LIU Manmen;SUN Xudong

作者机构：Key Laboratory for Anisotropy and Texture of Materials(Ministry of Education)Northeastern UniversityShenyang110819China State Key Laboratory of Advanced Technologies for Comprehensive Utilization of Platinum MetalsKunming Institute of Precious MetalsKunming 650106China 

出 版 物：《贵金属》 (Precious Metals)

年 卷 期：2012年第33卷第A1期

页      面：189-194页

学科分类：08[工学] 080502[工学-材料学] 0805[工学-材料科学与工程（可授工学、理学学位）] 

主　　题：ruthenium particles ammonium formate 

摘      要：Ruthenium, one of the platinum group metals, has drawn much attention due to its catalytic behavior, hardness, electrical conductivity and density. Ruthenium particles are usually prepared on a small scale by the polyol process, however, the size of the obtained ruthenium nanoparticles is most below 10 nm. In this work, ruthenium particles about 200 nm in diameter were obtained in aqueous solution by using ammonium formate as the reducing agent. To have a better control of particle s size and shape, the effects of PVP, mixing mode, reaction temperature, solution pH and calcination temperature were investigated.