IMPEDANCE CHARACTERISTICS OF POLYFURAN FILMS

作     者：Liang Li Xiao-bo Wan Gi Xue Department of Polymer the State Key Laboratory of Coordination Chemistry Nanjing University Nanjing 210093. China 

作者机构：Department of Polymer Nanjing University the State Key Laboratory of Coordination Chemistry Nanjing 210093 

出 版 物：《Chinese Journal of Polymer Science》 (高分子科学（英文版）)

年 卷 期：2002年第20卷第5期

页      面：419-423页

核心收录：

学科分类：0817[工学-化学工程与技术] 08[工学] 0805[工学-材料科学与工程（可授工学、理学学位）] 080502[工学-材料学] 0703[理学-化学] 

基　　金：This work was supported by the National Natural Science Foundation of China (No. 50133010) 

主　　题：polyfuran electrochemical impedance spectroscopy capacitance 

摘      要：Electrochemical impedance spectroscopy (EIS) was first used for the characterization of polyfuran (PFu) films that had been formed electrochemically on an Au electrode. The polyfuran was measured in high oxidation state, intermediate oxidation state and reduction state, respectively. As the oxidation level is increased, the ionic conductivity of PFu/BF4- increases. And impedance studies on PFu show that the anion BF4- appears to be mobile with a high diffusion coefficient of approximately 10(-8) cm(2).s(-1).