Visible light-mediated C—P bond formation reactions

作     者：Bao-Gui Cai Jun Xuan Wen-Jing Xiao 

作者机构：Anhui Province Key Laboratory of Chemistry for Inorganic/Organic Hybrid Functionalized Materials College of Chemistry & Chemical Engineering Anhui University Key Laboratory of Pesticide & Chemical Biology Ministry of Education College of Chemistry Central China Normal University 

出 版 物：《Science Bulletin》 (科学通报（英文版）)

年 卷 期：2019年第64卷第5期

页      面：337-350页

核心收录：

学科分类：07[理学] 

基　　金：supported by the National Natural Science Foundation of China(21702001) Open fund for Institute of Physical Science and Information Technology,Anhui University and the Start-up Grant from Anhui University 

主　　题：C-P bond formation Organophosphorus compounds Photoredox catalysis Visible light 

摘      要：Organophosphorus compounds have attracted continuous attention in materials science, agrochemical and pharmaceutical fields due to their unique bioactivities. Thus, the development of novel and robust manners for the construction new C—P bond has therefore gained great interests in synthetic organic chemistry. Because of their intrinsic sustainability and green chemistry character, visible light-induced photoredox catalysis has been widely applied in the construction of new chemical bonds, including the formation of C—P bond. In this review, we summarized recent achievements in C—P bond formation reactions initiated by visible light-induced photoredox catalysis, which mainly focusing on the discussion of reaction design and the mechanism.