A New Cobalt(Ⅱ)Polymer Based on 1-Butylben-zimidazole and Terephthalate Mixed-ligands:Crystal Structure and Weak Interactions

作     者：WANG Jian-Hua ZHENG Zhan-Ying WU Xiu-Mei WANG Xiu-Guang GUO Jian-Hua LIU Qing-Xiang 

作者机构：Tianjin Key Laboratory of Structure and Performance for Functional Molecule College of Chemistry and Life Science Tianjin Normal University Tianjin 300387 China State Key Laboratory of Element-organic Chemistry Nankai University Tianjin 300071 China 

出 版 物：《Chinese Journal of Structural Chemistry》 (结构化学（英文）)

年 卷 期：2010年第29卷第7期

页      面：1033-1038页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 0805[工学-材料科学与工程（可授工学、理学学位）] 080502[工学-材料学] 0703[理学-化学] 070301[理学-无机化学] 

基　　金：supported by the National Natural Science Foundation of China(No.20872111) the Natural Science Foundation of Tianjin(07JCYBJC00300) 

主　　题：benzimidazole terephthalic acid cobalt,π-π interactions 

摘      要：A new cobalt（Ⅱ） polymer with quasi-rectangular cavities, [Co（L）2（TP）·H2O]n 1 （L=1-butylbenzimidazole, TP = terephthalate ion） has been prepared by means of self-assembly of 1-butylbenzimidazole, terephthalic acid and Co（NO3）2·6H2O. The structure of 1 was characterized by X-ray diffraction analysis. In the crystal packing, 2-D supramolecular layers are formed via π-π stacking interactions. The fluorescence emission spectra of L and 1 are described.