Ce(DBM)3Phen doped poly(methyl methacrylate) for three-dimensional multilayered optical memory by femtosecond laser

作     者：JIU Hongfang ZHANG Lixin 

作者机构：Department of Chemistry North University of China Taiyuan 030051 China Department of Chemical Engineering North University of China Taiyuan 030051China 

出 版 物：《Journal of Rare Earths》 (稀土学报（英文版）)

年 卷 期：2009年第27卷第5期

页      面：786-789页

核心收录：

学科分类：080603[工学-有色金属冶金] 08[工学] 0806[工学-冶金工程] 

基　　金：Project supported by the Shanxi (20072194 and 20072185) Provincial Youth Technology Research Foundation of China 

主　　题：doped polymer cerium optical memory rare earths 

摘      要：The formation of submicrometer voids within Ce(DBM)3Phen doped poly(methyl methacrylate)(PMMA) was reported under multiphoton absorption excited by an infrared laser beam. The absorption spectra, photoluminescence and electron spin resonance (ESR) spectra before and after femtosecond laser irradiation were discussed. An ultrashort-pulsed laser beam with a pulse width of 200 femtosecond at a wavelength of 800 nm was focused into doped PMMA. The large changes in refractive index and the fluorescence associated with a void allowed conventional optical microscopy and reflection-type confocal microscopy to be used as detection methods. Voids could be arranged in a three-dimensional multilayered structure for high-density optical data storage. The separation of adjacent bits and layers were 4 and 16 μm, respectively.