高氯酸杂环配合物金属盐的激光起爆(英文)
Laser Initiation of Complex Perchlorates of d-Metals With Heterocyclic Ligands作者机构:Saint-Petersburg State Institute of Technology (Technical University)Russia
出 版 物:《含能材料》 (Chinese Journal of Energetic Materials)
年 卷 期:2006年第14卷第6期
页 面:401-405页
核心收录:
学科分类:081704[工学-应用化学] 07[理学] 070304[理学-物理化学(含∶化学物理)] 08[工学] 0817[工学-化学工程与技术] 0703[理学-化学]
摘 要:Several d-metal perchlorate complexes with 3-hydrazino-4-amino-5-R-1,2,4-triazoles as ligands (where R=H, CH3, SH) were investigated. It was shown that SH-group inhibited radical processes of thermal decomposition and burning of the complexes and also increased the thresholds of their Q-switch IR-laser initiation compared with the salts where as R=H, CH3-groups decreased the sensitivity of the metal complexes to laser initiation.