The Reaction Of Metal Trialkyls With Benzo[H]Quinolin-10-ol
The Reaction Of Metal Trialkyls With Benzo[H]Quinolin-10-ol作者机构:Department of Chemistry Nanjing University
出 版 物:《Chinese Chemical Letters》 (中国化学快报(英文版))
年 卷 期:1999年第10卷第10期
页 面:875-878页
核心收录:
学科分类:081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 0703[理学-化学] 070301[理学-无机化学]
主 题:metal trialkyls gallium indium MOCVD precursors X-ray crystal structure
摘 要:The reaction of the trialkyl metals (R3M, R = Me, Et; M = Ga, In) with benzo[h]quinolin-10-ol (HO-BQ) in a 1:1 molar ratio gave intramolecular N coordinated complexes R2M-O-BQ (M = Ga, R = Me 1, Et 2) and (R2In-O-BQ)(2) (M = In, R = Et 3,) in 80-90% yield. The molecular structures of complexes 1 and 3 have been established by X-ray crystallography.