Hot Corrosion Behaviors of Ni-14%Cr Alloys in Molten Sulfate

作     者：Lu Xudong Tian Sugui Shui Li Yu Xingfu 

作者机构：Shenyang University of Technology Shenyang 110023 China Shenyang Ligong University Shenyang 110168 China 

出 版 物：《稀有金属材料与工程》 (Rare Metal Materials and Engineering)

年 卷 期：2009年第38卷第A3期

页      面：17-19页

核心收录：

学科分类：0806[工学-冶金工程] 08[工学] 0805[工学-材料科学与工程（可授工学、理学学位）] 080502[工学-材料学] 

主　　题：腐蚀行为 镍 X射线衍射分析 合金 

摘      要：The corrosion behaviors and mechanism of Ni-14%Cr alloys in molten salt with Na2SO4 at 1000℃ was investigated by means of XRD analysis and SEM observation. Results show that the alloys were subjected to the accelerated corrosion in molten salt and the corrosion kinetic of the alloy obeys the parabolic law. On the other hand, the corrosion-resistance of the alloy could be improved significantly by increasing of chromium content. Corrosion products may be divided into three layers, i. e. NiCr2O4, CoCr2O4, CoNi2S4, AlWO3 and Al2O3 granule are included in the outside of the scales, the continuous Al2O3 layer is localed in intermediate layer, and the sulfides is in the internal layer. The Cr2S3 phase in Ni-14Cr prevents the S and O from the matrix of the alloy. The morphology examinations tend to support the sulphidization-basic dissolution model previously proposed for hot corrosion mechanism.