Novel fluorene-carzazole-based conjugated copolymers containing pyrazoline and benzothiazole segments for blue light-emitting materials

作     者：Hao Chen Xing Xu He Gang Yan Xian Rong Cai Ying Li Qing Jiang Ming Gui Xie 

作者机构：College of Chemistry Sichuan University Chengdu 610064 China 

出 版 物：《Chinese Chemical Letters》 (中国化学快报（英文版）)

年 卷 期：2007年第18卷第12期

页      面：1496-1500页

核心收录：

学科分类：08[工学] 0805[工学-材料科学与工程（可授工学、理学学位）] 080502[工学-材料学] 

基　　金：105142 

主　　题：Fluorene-carbazole copolymers Pyrazoline Bezothiazole 

摘      要：A series of novel fluorene-carbazole-based copolymers with pyrazoline and benzothiazole units were synthesized successfully through Suzuki coupling reactions. The molecular structures and thermal properties of these polymers were characterized by FTrIR, 1H NMR, DSC and TGA. GPC results indicated that the weight-average molecular weight （Mw） and polydispersity of these polymers were in range （12,0（0）-14,000） and （1.8-2.0）, respectively. The two resulting polymers have high photoluminescence quantum efficiency implying that they may be promising candidates for polymer light-emitting diodes （PLEDs）.