Rheological Behavior of Epoxy Resin Concentrated Dispersions
Rheological Behavior of Epoxy Resin Concentrated Dispersions作者机构:Institute of Chemistry Chinese Academy of Sciences Beijing 100080 China School of Basic Medical Science Cap. University of Medical Science Beijing 100054 China
出 版 物:《Chinese Chemical Letters》 (中国化学快报(英文版))
年 卷 期:1999年第10卷第10期
页 面:867-870页
核心收录:
学科分类:08[工学] 0805[工学-材料科学与工程(可授工学、理学学位)] 080502[工学-材料学] 0703[理学-化学]
主 题:rheological behavior waterborne dispersion bisphenol A epoxy resin
摘 要:For the concentrated dispersions of epoxy resin prepared by phase inversion emulsification technique, the effects of solid content and temperature on the rheological behavior are studied. It is found that there exists reversible structural transition in concentrated dispersions subjected to shearing. The viscosity oscillation correlated with high viscoelasticity at lower stress is remarkable in highly concentrated dispersions. There exists storage modules overshot at higher stress during the dynamic stress time ramp test. This could provide some information on dynamics of structure changes during shear action. Besides, the effects of solid content and temperature on the relationship between tangent delta and frequency are essentially different.