Improved efficiency of ternary the blend polymer solar cells by doping a narrow band gap polymer material
Improved efficiency of ternary the blend polymer solar cells by doping a narrow band gap polymer material作者机构:Key Laboratory of Luminescence and Optical Information Ministry of Education Beijing Jiaotong University School of Electrical Engineering Beijing Jiaotong University
出 版 物:《Science China(Physics,Mechanics & Astronomy)》 (中国科学:物理学、力学、天文学(英文版))
年 卷 期:2015年第58卷第3期
页 面:59-63页
核心收录:
学科分类:08[工学] 080502[工学-材料学] 0805[工学-材料科学与工程(可授工学、理学学位)] 0803[工学-光学工程]
基 金:supported by the Fundamental Research Funds for the Central Universities(Grant No.2013JBZ004) the National Natural Science Foundation of China(Grant No.61377029) the Beijing Natural Science Foundation(Grant No.2122050) the State Key Laboratory of Catalysis,Chinese Academy of Sciences(Grant No.n-11-09)
主 题:ternary blend polymer solar cells exciton dissociation charge carrier transport
摘 要:A series of P3HT:PC71BM polymer solar cells (PSCs) with different PIDTDTQx doping concentrations were fabricated to in- vestigate the effect of the PIDTDTQx as a complementary electron donor on the performance of PSCs. The power conversion efficiency (PCE) of the optimized ternary blend PSCs (with 2 wt% PIDTDTQx) reached 3.87%, which is 28% higher than that of the PSCs based on P3HT:PCvlBM (control cells). The short-circuit current density (J^c) was increased to 10.20 mA/cm2 compared with the control cells. The PCE improvement could be attributed to more photon harvest and charge carrier transport by appropriate doping PIDTDTQx. The energy transfer from P3HT to PIDTDTQx was demonstrated from the 650 nm emis- sion intensity decrease and the red-shifted emission peaks from 725 nm to 737 nm along with the increase of PIDTDTQx dop- ing concentrations.