Performance of water-based foams affected by chemical inhibitors to retard spontaneous combustion of coal
Performance of water-based foams affected by chemical inhibitors to retard spontaneous combustion of coal作者机构:School of Resource and Safety Engineering China University of Mining & Technology
出 版 物:《International Journal of Mining Science and Technology》 (矿业科学技术学报(英文版))
年 卷 期:2016年第26卷第3期
页 面:443-448页
核心收录:
学科分类:0808[工学-电气工程] 0709[理学-地质学] 0819[工学-矿业工程] 081903[工学-安全技术及工程] 08[工学] 0807[工学-动力工程及工程热物理] 0708[理学-地球物理学] 0818[工学-地质资源与地质工程] 0815[工学-水利工程] 0813[工学-建筑学] 0814[工学-土木工程]
基 金:supported by the National Natural Science Foundation of China(No.51274205) the State Key Laboratory for Coal Resources and Safe Mining,China University of Mining&Technology(No.SKLCRSM10KFB13) the Hebei Key Laboratory for Mine Disaster Prevention of China(No.KJZH2013K02)
主 题:Coal spontaneous combustion Chemical inhibitors Micelle thermal power Foam performance Activation energy
摘 要:The micelle generating process of the sodium dodecyl sulfate(SDS) solution with the addition of chemical inhibitors was elucidated using phase separation model, and the descending order of the capacity for the selected chemical inhibitors to reduce the critical micelle concentrations of the solution are Mg Cl_2, Ca Cl_2,NH_4HCO_3 and NH_4Cl. The data to quantitatively describe the foam decay process, including foaming ratio,foam life and decay behaviors, was obtained by pressure measuring system. The results indicate that chemical inhibitors can improve the solution foamability. The capacity of the inhibitors to enhance the solution foamability is sorted as NH_4 Cl, NH_4HCO_3, Mg Cl2 and Ca Cl_2 which can distinctly improve the foam stability as well. The capacity of the inhibitors to enhance the SDS foam stability can be arranged as Mg Cl_2, NH_4 Cl, NH_4HCO_3 and Ca Cl_2. It is observed that the gravity drainage plays a leading role in the increase of proportion of diffusion drainage. The oxidation dynamic parameters of the coal samples treated by inhibition foams were investigated using thermal analysis technique, and their synergistic effects on inhibiting coal oxidation were explored.