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Studies on the synthesis of amino acids ***-liquid phase transfer catalytic dicondensation of 1,4-diacety1-2,5-piperazinedione with aldehydes

Studies on the synthesis of amino acids ***-liquid phase transfer catalytic dicondensation of 1,4-diacety1-2,5-piperazinedione with aldehydes

作     者:DU,Zheng-Ming ZHOU,Xiao-Ming SHI,Yao-Zeng HU,Hong-Wen Department of Chemistry,Nanjing University,Nanjing 210008 

作者机构:Department of Chemistry Nanjing University Nanjing 210008 

出 版 物:《Chinese Journal of Chemistry》 (中国化学(英文版))

年 卷 期:1992年第10卷第1期

页      面:82-88页

核心收录:

学科分类:07[理学] 0703[理学-化学] 

基  金:Project supported by the National Natural Science Foundation of China and Modern Analysis Centre of Nanjing University 

主  题:PDO KBr Studies on the synthesis of amino acids XII.Solid-liquid phase transfer catalytic dicondensation of 1,4-diacety1-2,5-piperazinedione with aldehydes ppm 

摘      要:3,6-Diarylidene-2,5-piperazinediones(2)and 3-alkylidene-6-arylidene-2,5-piperazfnediones (6)were synthesized from diacetyl-2,5-piperazinedione(1)under solid-liquid phase transfer catalytic conditions.2 could be easily convered to a-amino acid by reducing with zinc powder and hydrolyzing with concentrated hydrochloric *** effect of different phase transfer catalysts and reaction con- ditions were studied.

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