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Electrochemical properties of LiNi_(0.5)Mn_(1.3)Ti_(0.2)O_4/Li_4Ti_5O_(12)cells

Electrochemical properties of LiNi_(0.5)Mn_(1.3)Ti_(0.2)O_4/Li_4Ti_5O_(12)cells

作     者:Guo-qiang Liu Xi Wang Ya-jie Gao Lei Wen Guang-yin Liu Jian-jie Zheng Peng Cen Ying Li 

作者机构:School of Materials and Metallurgy Northeastern University Shenyang 110004 China Institute of Metal Research Chinese Academy of Sciences Shenyang 110016 China 

出 版 物:《International Journal of Minerals,Metallurgy and Materials》 (矿物冶金与材料学报(英文版))

年 卷 期:2012年第19卷第5期

页      面:457-460页

核心收录:

学科分类:081702[工学-化学工艺] 0709[理学-地质学] 0819[工学-矿业工程] 08[工学] 0806[工学-冶金工程] 0817[工学-化学工程与技术] 0708[理学-地球物理学] 0805[工学-材料科学与工程(可授工学、理学学位)] 080502[工学-材料学] 0703[理学-化学] 0802[工学-机械工程] 0801[工学-力学(可授工学、理学学位)] 0702[理学-物理学] 

基  金:supported by the National Natural Science Foundation of China (No.51074038) the Training Program on National College Students’ Innovation Experiment (No.110126) 

主  题:lithium batteries titanium compounds nickel compounds manganese compounds oxides electrochemical properties 

摘      要:Spinel compounds LiNi0.5Mn1.3Ti0.2O4(LNMTO) and Li4Ti5O12 (LTO) were synthesized by different methods. The particle sizes of LNMTO and LTO are 0.5-2 and 0.5-0.8 μm, respectively. The LNMTO/LTO cell exhibits better electrochemical properties at both a low current rate of 0.2C and a high current rate of 1C. When the specific capacity was determined based on the mass of the LNMTO cathode, the LNMTO/LTO cell delivered 137 mA.h.g-1 at 0.2C and 118.2 mA-h-g-l at 1C, and the corresponding capacity retentions after 30 cycles are 88.5% and 92.4%, respectively.

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