Synthesis and spectral characterization of lanthanide complexes with 1,2-diphenyl-4-butyl-3,5-pyrazolidinedione: Luminescent property of Tb(Ⅲ) complex

作     者：M.R.Anoop P.S.Binil S.Suma M.R.Sudarsanakumar 

作者机构：Department of Chemistry S.N. College Department of Chemistry S.N .College Depart-ment of Chemistry M.G. College 

出 版 物：《Journal of Rare Earths》 (稀土学报（英文版）)

年 卷 期：2012年第30卷第7期

页      面：709-715页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学] 

基　　金：support from the University of Kerala for the award of afellowship 

主　　题：lanthanide complexes IR thermal analysis luminescent properties rare earths 

摘      要：The complexes of rare earth elements with 1,2-diphenyl-4-butyl-3,5-Pyrazolidinedione （PBH, phenylbutazone） were synthesized and characterized by elemental analysis, molar conductance, IR, UV-Vis, EPR and magnetic moment measurements. Based on these studies the complexes were formulated as [Ln（PB）3（H2O）2].nH2O, where Ln=Eu（III）, Gd（III）, Tb（III）, Dy（III） and Er（III）. From IR spectra, it was found that PBH acted as a bidentate mono-ionic ligand coordinating through two carbonyl oxygen of the pyrazolidinedione ring. The thermal analysis of all the complexes was carried out at a heating rate of 10 oC/min. The kinetic aspects of the complexes were evaluated. The nega-tive entropy value of the complexes indicated a more ordered state for the activated complexes. The photoluminescence property of Tb（III） complex was investigated. It showed all the characteristic emission peaks of Tb^3＋ with a life time of 0.98914 ms.