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Influences of Reactive Compatibilizer R-Styrene-Maleic Anhydride Copolymer on PA6/PP Blends

Influences of Reactive Compatibilizer R-Styrene-Maleic Anhydride Copolymer on PA6/PP Blends

作     者:黄伯芬 李枭 梁翰轩 Jeffrey X Shi 王俊杰 李知远 

作者机构:School of Materials Science and EngineeringNanchang University School of Electromechanical EngineeringEast China Jiaotong University School of Chemical and Biomolecular EngineeringThe University of Sydney 

出 版 物:《Journal of Donghua University(English Edition)》 (东华大学学报(英文版))

年 卷 期:2011年第28卷第4期

页      面:367-370页

核心收录:

学科分类:0817[工学-化学工程与技术] 08[工学] 0807[工学-动力工程及工程热物理] 0805[工学-材料科学与工程(可授工学、理学学位)] 080502[工学-材料学] 0802[工学-机械工程] 0811[工学-控制科学与工程] 

基  金:Science and Technology Program from Jiangxi Provincial Department of Education China (No. CJJ10377) 

主  题:Nylon 6/polypropylene blends R-styrene-maleic anhydride copolymer ( R-SMA ) compatibilization morphology crystallinity properties 

摘      要:The effect of R-styrene-maleic anhydride copolymer (R- SMA) compatibilzation on Nylon 6 ( PA6 )/polypropylene ( PP ) blends has been investigated experimentally through Molan test, microscopic morphology, and chemical structure. Results show that the moderate R-SMA addition can promote reaction between anhydride in R-SMA and amino in PA6, and lead to a new PA6-g- R-SMA copolymer in the blends. Such PA6-g-R-SMA eopolymer in the blends can effectively reduce the interfaeial tension and PP particle size, and improve the compatibility of two immiscible phases in the blends. The crystallinity of PA6 in PA6/PP blends has greatly decreased by PP blends. The blends have the best comprehensive mechanical and thermal properties when the mass ratio of PA6/PP/ R-SMA is 90:10:2 to 90:10:4. The impact strength of the PA6/PP blends with the eompatibilizer is increased by more than 150 %.

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