Electronic States in Trans-CoCl<sub>2</sub>(H<sub>2</sub>O)<sub>4</sub>Complex
Electronic States in Trans-CoCl<sub>2</sub>(H<sub>2</sub>O)<sub>4</sub>Complex作者机构:不详
出 版 物:《Materials Sciences and Applications》 (材料科学与应用期刊(英文))
年 卷 期:2011年第2卷第8期
页 面:1121-1126页
主 题:Crystal And Ligand Fields Transition-Metal Compounds CoCl2(H2O)4 Chromophore
摘 要:The polarized absorption spectra of cobalt(II) in trans-CoCl2(H2O)4.2H2O provides important information about the electronic structure. Semi-empirical calculation of the crystal-field levels of the cobalt(II) with D4h point group symmetry in CoCl2(H2O)4.2H2O are carried out, leading to a good agreement between the theoretical and experimental energy levels.