SYNTHESIS OF POLYMERS CONTAINING N-N LINKAGES

作     者：Zaza Gomurashvili Allan S.Hay 

作者机构：Department of Chemistry McGill University 801 Sherbrooke Street West Montreal Ouebec Canada H3A 2K6Department of Chemistry McGill University 801 Sherbrooke Street West Montreal Ouebec Canada H3A 2K6 

出 版 物：《Chinese Journal of Polymer Science》 (高分子科学（英文版）)

年 卷 期：2003年第21卷第5期

页      面：541-550页

核心收录：

学科分类：08[工学] 0805[工学-材料科学与工程（可授工学、理学学位）] 080502[工学-材料学] 

主　　题：Hydrazine N-N-linkage N-aminoimide Poly(imidoaryll ether) N-aminotriazole Polyazine 

摘      要：The N--N linkage in hydrazine is thermally stable when it is tetrasubstituted and there are electron-withdrawinggroups attached to the nitrogen atoms. Our research on the synthesis of polymers contaning N--N linkages is reviewed. TheN,N-bisimide structure has been introduced in the backbone of polymers as well as a pendant group in poly(aryl ether)s togive very thermoxidatively stable polymers with very high glass transition temperatures. Most of the polymers form tough,flexible films. N-Aminotriazoles also form stable imides by reaction with anhydrides and these N-imidotriazole groups havebeen introduced as pendent groups on poly(aryl ether)s. The polymers are highly fluorescent materials. Three methods for thesynthesis of polymers containing the tetrasubstituted-azine structure will be discussed: (1) oxidative coupling of bisimines;(2) condensation of bishydrazones with diketones; (3) poly(aryl ether azines) from the azine formed from 4-fluorobenzo-phenone by reaction with salts of bisphenols.