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Study of the (Ca<sub>1–x</sub>Sr<sub>x</sub>) RuO<sub>3</sub>System with Nano-Crystals Prepared by the Solid-State Reaction Method

Study of the (Ca<sub>1–x</sub>Sr<sub>x</sub>) RuO<sub>3</sub>System with Nano-Crystals Prepared by the Solid-State Reaction Method

作     者:Adolfo Quiroz Elizabeth Chavira José Eduardo Espinosa Rodolfo Palomino-Merino Ernesto Esteban Marinero Masaya Nishioka Valentín García-Vázquez 

作者机构:Facultad de Ciencias Fí sico-Matemá ticas Postgrado en Fí sica Aplicada Benemé rita Universidad Autónoma Puebla Ciudad Universitaria Puebla Mé xico Instituto de Investigaciones en Materiales Universidad Nacional Autónoma de Mé xico Mé xico D.F. Mé xico Purdue University West Lafayette IN USA Hitachi San José Research Center San José  California USA Instituto de Fí sica LRT Benemé rita Universidad Autónoma de Puebla Puebla Mé xico 

出 版 物:《Materials Sciences and Applications》 (材料科学与应用期刊(英文))

年 卷 期:2015年第6卷第1期

页      面:16-22页

学科分类:07[理学] 0703[理学-化学] 

主  题:Solid-State Reaction XRD SEM Electric Resistivity Magnetic Properties 

摘      要:We present a study of their structure, morphology, electrical and magnetic properties on the (Ca1–xSrx) RuO3 system for x = 0.0, 0.07, 0.10, 0.15 and 1.0. The samples were prepared by the solidstate reaction method in air at ambient pressure and heat in the 700℃ - 800℃ range for 48 h. By X-ray powder diffraction (XRD), we determine a solid solution until x = 0.15. Scanning electron microscopy (SEM) indicates that the particle size is 77 - 266 nm. The resistance measurements, as a function of temperature measurements from 7 to 300 K the (Ca1–xSrx) RuO3 system for x = 0.0, 0.07, 0.10, 0.15 and 1.0 show a metallic behaviour. We can even observe that the resistance of the samples is due to the partial substitution of Sr2+ ions and Ru ion valence. Finally, the sample x = 0.07 has a magnetization applied high field to 10 K, whereas that to 300 K does not have a magnetization.

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