The green fuel from carbon waste： optimization and product selectivity model studies

作     者：Hossein Atashi Fatemeh Rezaeian Ali Akbar Mirzaei 

作者机构：Department of Chemical Engineering University of Sistan and Baluchestan Zahedan Iran Department of Chemistry University of Sistan and Baluchestan Zahedan Iran 

出 版 物：《International Journal of Coal Science & Technology》 (国际煤炭科学技术学报（英文）)

年 卷 期：2018年第5卷第3期

页      面：399-410页

核心收录：

学科分类：081702[工学-化学工艺] 08[工学] 0817[工学-化学工程与技术] 0802[工学-机械工程] 

基　　金：Ministry of Science & Research Sistan and Baluchestan 

主　　题：Selectivity model Fischer-Tropsch synthesis Green fuel Optimization Fixed bed micro reactor Alternative fuels 

摘      要：Increase in greenhouse gases, has made scientists to substitute alternative fuels for fossil fuels. Nowadays, converting biomass into liquid by Fischer-Tropsch synthesis is a major concern for alternative fuels （gasoline, diesel etc.）. Selectivity of Fischer-Tropsch hydrocarbon product （green fuel） is an important issue. In this study, the experimental data has been obtained from three factors; temperature, H2/CO ratio and pressure in the fixed bed micro reactor. T = 543-618 （K）, P = 3-10 （bar）, H2/CO = 1-2 and space velocity = 4500 （l/h） were the reactor conditions. The results of product modeling for methane （CH4）, ethane （C2H6）, ethylene （C2H4） and CO conversion with experimental data were compared. The effective parameters and the interaction between them were investigated in the model. H2/CO ratio and pressure and interaction between pressure and H2/CO in ethane selectivity model and CO conversion and interaction between temperature and H2/CO ratio in methane selectivity model and ethylene gave the best results. To determine the optimal conditions for light hydrocarbons, ANOVA and RSM were employed. Finally, products optimization was done and results were concluded.