PVC DISULFIDE AS CATHODE MATERIALS FOR SECONDARY LITHIUM BATTERIES

作     者：Guo-xiang Xu 其鲁 Bi-tao Yu Lei Wen 

作者机构：Department of Applied Chemistry College of Chemistry and Molecular Engineering Peking University Beijing 100871 China Department of lnorganic Nonmetal Materials School of Materials Science and Engineering University of Science and Technology Beijing Beijing 100083 China 

出 版 物：《Chinese Journal of Polymer Science》 (高分子科学（英文版）)

年 卷 期：2006年第24卷第3期

页      面：307-313页

核心收录：

学科分类：080801[工学-电机与电器] 0808[工学-电气工程] 08[工学] 0805[工学-材料科学与工程（可授工学、理学学位）] 080502[工学-材料学] 

主　　题：PVC disulfide (2SPVC) Cathode Lithium battery Capacity Cycle. 

摘      要：PVC disulfide （2SPVC） was synthesized by solution crosslink and its molecular structure was confirmed by infrared spectrum. 2SPVC＇s specific area is 36.1 m^2·g^-1 tested by stand BET method, and granularity experiment gives out the particle size of d0.5 = 11.3 μm. With SEM （Scanning Electron Microscope） experiment the surface morphology and particle shape of 2SPVC were observed. Cyclic voltammetry （scan rate： 0.5 mV · s^-1） shows that 2SPVC experience an obvious S-S redox reaction in charge-discharge process. When 2SPVC was used as cathode material for secondary lithium battery in a 1 mol·L^-1 solution of lithium bis（trifluoromethylsulfonyl） imide （Li（CF3SO2）2N） in a 5：45：50 volume ratio mixture of o-xylene （oxy）, diglyme （DG） and dimethoxymethane （DME） at 30℃, the first discharge capacity of 2SPVC is about 400.3 mAh·g^-1 which is very close to its theoretical value （410.5 mAh ·g^-1） at a constant discharge current of 15 mA·g^-1. It can retain at about 346.1 mAh ·g^-1 of discharge capacity after 30 charge-discharge cycles. So 2SPVC is a very promising cathode candidate for rechargeable lithium batteries.