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Dielectric and microstructural properties of YAG:Dy^(3+) ceramics

Dielectric and microstructural properties of YAG:Dy^(3+) ceramics

作     者:Munirah Abdullah Almessiere Bayram Unal Abdulhadi Baykal 

作者机构:Department of Physics College of Science Imam Abdulrahman Bin Faisal University Department of Nanomedicine Research Institute for Research & Medical Consultations (IRMC) Imam Abdulrahman Bin Faisal University Department of Software and Computer Engineering Istanbul Sabahattin Zaim University 

出 版 物:《Journal of Rare Earths》 (稀土学报(英文版))

年 卷 期:2018年第36卷第12期

页      面:1310-1318页

核心收录:

学科分类:0709[理学-地质学] 0819[工学-矿业工程] 08[工学] 0708[理学-地球物理学] 0805[工学-材料科学与工程(可授工学、理学学位)] 080502[工学-材料学] 0703[理学-化学] 

主  题:Yttrium aluminium garnet(YAG) X-ray diffraction(XRD) Conductivity Dielectric properties Rare earths 

摘      要:Yttrium aluminium garnet(Y3Al5O12:YAG) singly doped with Dy3+ at different concentrations was prepared by solid state reactions using repeated heating cycles over the temperature range of 1300-1600 ℃. X-ray powder diffraction analysis confirms the presence of a well-crystallized YAG perovskite phase with cubic structure(by Rietveld refinement). The rare earth dopant is successfully integrated into the YAG host lattice without any major changes in the original structure. The temperature dependence,up to 250 ℃, of the conductivity, dielectric constant, dielectric loss, and loss tangent, at various frequencies of up to 5.0 MHz for undoped and doped crystals is compared to understand the electrical and structural characteristics. The experimental results reveal that Dy3+ dopants in YAG crystal significantly influence the conductivity, dielectric constant, and lossy mechanisms, which is probably due to the 3 d-AI ions and 4 f-Dy ions incorporated at different positions of both tetrahedral and octahedral symmetries in YAG:xDy3+ ceramics.

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