Kinetic study on desulfurization and denitrification using microwave irradiation over activated carbon

作     者：MA ShuangChen YAO Juan Juan JIN Xin ZHANG Bo 

作者机构：School of Environment North China Electric Power University Baoding 071003 China 

出 版 物：《Science China(Technological Sciences)》 (中国科学（技术科学英文版）)

年 卷 期：2011年第54卷第9期

页      面：2321-2326页

核心收录：

学科分类：083002[工学-环境工程] 0830[工学-环境科学与工程（可授工学、理学、农学学位）] 081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070305[理学-高分子化学与物理] 080501[工学-材料物理与化学] 0805[工学-材料科学与工程（可授工学、理学学位）] 0703[理学-化学] 

基　　金：supported by the National Natural Science Foundation of China (Grant No. 50976035) 

主　　题：microwave desulfurization denitrification kinetics 

摘      要：Sulfur dioxide （SO2） and nitrogen oxide （NOx） in flue gas can be removed by combining microwave induced catalysis and adsorption on activated carbon. The reaction mechanisms of desulfurization and denitrification by microwave irradiation were analyzed based on the measurement of reaction products. Thermodynamic parameters for desulfurization and denitrification by thermal-carbon reduction were predicted according to the principles of thermodynamics. The experimental results indicated that the desulfurization and denitrification reaction processes include three reaction stages： slow reaction zone, transitional zone and rapid reaction zone. In high temperature zone, activation energies for the reduction of SO2 and nitrogen monoxide （NO） are 30.69 and 24.06 kJ mo1-1, respectively. This study shows that microwave can effectively enhance the removal of pollutants through its heating effect and the induced catalysis.