Mobility and sulfidization of heavy metals in sediments of a shallow eutrophic lake, Lake Taihu, China
Mobility and sulfidization of heavy metals in sediments of a shallow eutrophic lake, Lake Taihu, China作者机构:State Key Laboratory of Environmental Criteria and Risk Assessment Chinese Research Academy of Environmental Science Department Earth and Environmental Sciences University of Kentucky
出 版 物:《Journal of Environmental Sciences》 (环境科学学报(英文版))
年 卷 期:2015年第27卷第5期
页 面:1-11页
核心收录:
学科分类:081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 0815[工学-水利工程] 0703[理学-化学] 070301[理学-无机化学]
基 金:supported by the Mega-projects of Science Research for Water Environment Improvement (No. 2012ZX07101-002) the National Natural Science Foundation of China (No. 41303085)
主 题:Sulfidization process Heavy metals DGT(diffusive gradients in thin films)
摘 要:The technique of DGT(diffusive gradients in thin films) using three diffusive gel thicknesses was applied to estimate the mobility and bioavailability of heavy metals in sediments and porewater of Lake Taihu, China. The DGT results showed significantly positive correlations between Co, Pb, Cd and Mn, and Ni and Fe concentrations in porewater. Cu and Zn showed a significantly negative correlation with Mn, due to Cu combination with carbonates and Zn derived from agricultural pollution, respectively. The rank order of average concentrations of Co, Ni and Cd at each station was DGT1.92〉DGT0.78〉 DGT0.39, suggesting stronger resupply from sediments to porewater when using thicker diffusive gels. Comparing centrifugation and DGT measurements, Co, Ni and Cd are highly labile; Mn and Fe are moderately labile; and Cu, Zn and Pb are slightly labile. The variations of AVS concentrations in sediment cores indicate that metal sulfides in deeper layers are easily diffused into surface sediments.