Oleanane-triterpene Saponins from Clinopodium urticifolium

作     者：Li Ming GAO, Xiao Mei WEI, Dong Liang CHENGDepartment of Chemistry, National Laboratory of Applied Organic Chemistry,Lanzhou University, Lanzhou 730000 Department of Chemistry, Northwest Normal University, Lanzhou 730070 

作者机构：Department of Chemistry National Laboratory of Applied Organic Chemistry Department of Chemistry Northwest Normal University 

出 版 物：《Chinese Chemical Letters》 (中国化学快报（英文版）)

年 卷 期：2003年第14卷第10期

页      面：1041-1044页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学] 

基　　金：the National Laboratory of Applied Organic Chemistry,Lanzhou University for NMR,HRESIMS to the National Natural Science Foundation of China for financial support(No.29772010) 

主　　题：Clinopodium urticifolium Labiatae oleanane triterpene saponins. 

摘      要：Four new oleanane triterpene saponins were isolated and purified from the whole plant of Clinopodium urticifolium. They were 3B 16B, 23, 28-tetrahydroxyoleana-9 (11), 12(13)-diene-3-yl-[B-D-glucopyranosyl-(1-2)]-[B-D-glucopyranosyl-(1-3)]- B-D-fucopyranoside 1; 3B, 16B, 21B, 23, 28-pentahydroxyoleana-9(11), 12(13)-diene-3-yl-[B-D-glucopyranosyl-(1-2)]-[B-D-glucopyranosyl-(1-3)]- B-D-fucopyranoside 2; 3B, 16B, 23, 28-tetrahydroxyoleana-9(11), 12(13)-diene-3-yl-[B-D-glucopyranosyl-(1-6)-B-D-glucopyranosyl-(1-3)]-[B-D-glucopyranosyl-(1-2)]-B-D-fucopyranoside 3; 3B, 16B, 23, 28-tetrahydroxyoleana-9(11), 12(13)-diene-3-yl-[B-D-gluco-pyranosyl-(1-4)-B-D-glucopyranosyl-(1-6)-B-D-glucopyranosyl-(1-3)]-[B-D-glucopyranosyl-(1-2)]- B-D-fucopyranoside 4. Their structures were elucidated on the basis of interpretation of NMR and MS data and from chemical evidence.