Transition Metal Catalyzed Direct Oxidative Borylation of C--H Bonds

作     者：Zhong-Tao Jiang Bi-qin Wang Zhang-Jie Shi 

作者机构：College of Chemistry and Materials Science Sichuan Normal University Chengdu Sichuan 610068 China Department of Chemistry Fudan University Shanghai 200433 China 

出 版 物：《Chinese Journal of Chemistry》 (中国化学（英文版）)

年 卷 期：2018年第36卷第10期

页      面：950-954页

核心收录：

学科分类：081702[工学-化学工艺] 081705[工学-工业催化] 08[工学] 0817[工学-化学工程与技术] 080502[工学-材料学] 0805[工学-材料科学与工程（可授工学、理学学位）] 0703[理学-化学] 

主　　题：C-H borylation oxidation organoboron transition metal catalysis 

摘      要：Organoboron is well-developed and broadly utilized organometallic reagents in organic synthesis due to its extraordinary performances in transition-metal catalyzed C-C and C-X bonds construction. Catalytic C--H borylation and further transformations catalyzed by transition metal catalysts in the absence of oxidants were well studied in decades. However, as known, transition metal catalyzed oxidative C-H borylations were not reviewed up to date. In this article the oxidative borylation of C（sp2）-H and C（sp3）-H bonds were summarized and their mechanisms were also accounted.