Two-dimensional correlation spectroscopic studies on coordination between carbonyl group of butanone and metal ions

作     者：Dan-Qing Gao Xiao-Pei Li Jia-Jia Shi Xiao-Yan Kang Ting-Guo Kang Jin-Ming Xia Xiao-Feng Ling Shi-Fu Weng Yi-Zhuang Xu Isao Noda Jin-Guang Wu 

作者机构：School of PostgraduateLiaoning University of Traditional Chinese Medicine College of Chemistry and Molecular EngineeringPeking University Institute of Process Engineering and Chinese Academy of Sciences College of Chemistry and MaterialsHebei Normal University Two Five Eight Health Technology Co.Ltd The Third School of Clinical Medicine of Peking University Ninghai Doubly Advanced Material Co.Ltd Department of Materials Science and EngineeringUniversity of Delaware 

出 版 物：《Chinese Chemical Letters》 (中国化学快报（英文版）)

年 卷 期：2015年第26卷第2期

页      面：177-181页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 070304[理学-物理化学(含∶化学物理)] 08[工学] 0817[工学-化学工程与技术] 070302[理学-分析化学] 0703[理学-化学] 

基　　金：financially supported by the National Natural Science Foundation of China(No.51373003) Beijing Natural Science Foundation(No.2122059) 

主　　题：Ca^2+ Al^3+ Butanone Coordination 2D correlation spectroscopy 

摘      要：Two dimensional asynchronous spectra were used to characterize coordination between carbonyl group of butanone and metal ions by using an approach proposed in our recent *** variation of n-π^＊transition band of carbonyl group is used to probe the coordination even if metal ions does not possess any characteristic peak in *** results indicate that Ca^2＋ and Al^3＋ show considerable ability to coordinate with the carbonyl group of butanone and bring about spectral variation of the n-π-＊transition band,which is manifested by cross peaks in 2D asynchronous spectra.