Electrode process of diethyldithiocarbamate on surface of pyrrhotite

作     者：黎维中 覃文庆 邱冠周 董清海 

作者机构：School of Resources Processing and Bioengineering Central South University Changsha 410083 China General 

出 版 物：《Journal of Central South University of Technology》 (中南工业大学学报（英文版）)

年 卷 期：2005年第12卷第4期

页      面：416-419页

核心收录：

学科分类：081902[工学-矿物加工工程] 0819[工学-矿业工程] 08[工学] 

基　　金：Project(50204013)supportedbytheNationalNaturalScienceFoundationofChina 

主　　题：electrode process pyrrhotite diethyldithiocarbamate 

摘      要：The electrode process of diethyldithiocarbamate on the surface of pyrrhotite was studied using systematic electrochemical analysis, including cyclic voltammetry, chronopotentiometry and galvanostatic. Experimental results show that tetraethylthioram disulphide（TETD） is electrodeposited on pyrrhotite electrode surface in the presence of 1.0×10^-4 mol/L diethyldithiocarbamate when the electrode potential is higher than 0.25 V. The electrochemical kinetics parameters of the electrode process of diethyldithiocarbamate on surface of pyrrhotite are calculated as follows： the exchange current density is 2.48μA/cm^2 , and the transmission coefficient is 0.46. The electrodeposition includes two steps electrochemical reaction. The first reaction is electrochemical adsorption of diethyldithiocarbamatc ion, then the adsorbed ion associates with a diethyldithiocarbamate ion from the solution and forms tetraethylthioram disulphide on the surface of pyrrhotite.