The novel usage of thiourea nitrate in aryl nitration

作     者：Ge Meng Mei-Lin Zheng A-Qun Zheng Mei Wang Juan Shi 

作者机构：School of PharmacyXi’an Jiaotong University School of ScienceXi’an Jiaotong University 

出 版 物：《Chinese Chemical Letters》 (中国化学快报（英文版）)

年 卷 期：2014年第25卷第1期

页      面：87-89页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学] 

基　　金：Fundamental Research Funds for the Central Universities(2011) Scientific Research Foundation for the Returned Overseas Chinese Scholars,State Education Ministry,PR China(2011)for the financial support 

主　　题：Thiourea nitrate Nitration Thiourea Aromatic compounds 

摘      要：Thiourea nitrate （TN） was easily prepared from thiourea and nitric acid to explore its use as a new nitration reagent, Nitrations of various aromatic compounds utilizing TN in concentrated sulfuric acid were studied, TN could convert aromatic compounds to the corresponding nitrated derivatives with various abnormal yields under mild conditions. The results suggested that the reaction mechanism might be different from those of traditional nitration reagents.