Synthesis of Spiro Dihydrofurans and 1,8-Dioxo-xanthenes via DABCO Catalyzed Tandem Reaction of Aldehyde with Cyclohexane-1,3-dione and Dimedone

作     者：CHEN Jiao SHI Jian YAN Chao-guo 

作者机构：College of Chemistry ＆ Chemical Engineering Yangzhou University Yangzhou 225002 P. R. China 

出 版 物：《Chemical Research in Chinese Universities》 (高等学校化学研究（英文版）)

年 卷 期：2011年第27卷第1期

页      面：49-53页

核心收录：

学科分类：081705[工学-工业催化] 08[工学] 0817[工学-化学工程与技术] 080502[工学-材料学] 0805[工学-材料科学与工程（可授工学、理学学位）] 

基　　金：Supported by the National Natural Science Foundation of China(No20972132) 

主　　题：Tandem reaction Dimedone Spiro dihydrofuran Tetraketone 1,8-Dioxo-xanthene 

摘      要：The 1,4-diazabicyclo[2.2.2]octane（DABCO） catalyzed reaction of cyclohexane-1,3-dione or dimedone with various aldehydes in acetonitrile resulted in the polysubstituted tetraketones, spiro dihydrofurans or 1,8-dioxo-xanthenes derivatives as main products respectively according to the structure of reactants and reaction conditions.