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Advanced Na metal anodes

Advanced Na metal anodes

作     者:Chenglong Zhao Yaxiang Lu Jinming Yue Du Pan Yuruo Qi Yong-Sheng Hu Liquan Chen 

作者机构:Key Laboratory for Renewable Energy Beijing Key Laboratory for New Energy Materials and Devices Beijing National Laboratory for Condensed Matter Physics Institute of Physics Chinese Academy of Sciences Beijing 100190 China School of Physical Sciences University of Chinese Academy of SciencesBeijing 100190 China 

出 版 物:《Journal of Energy Chemistry》 (能源化学(英文版))

年 卷 期:2018年第27卷第6期

页      面:1584-1596页

核心收录:

学科分类:0820[工学-石油与天然气工程] 0808[工学-电气工程] 0817[工学-化学工程与技术] 08[工学] 0807[工学-动力工程及工程热物理] 0827[工学-核科学与技术] 0703[理学-化学] 

基  金:supported by the National Key Technologies R&D Program,China (2016YFB0901500) the National Natural Science Foundation of China (51672275,51421002) 

主  题:Na metal anode Solid electrolyte interphase Electrolyte Dendrite Na-metal batteries 

摘      要:Na metal anode, benefiting from its high theoretical capacity and lowest electrochemical potential, ~sone of the most favorable candidates for future Na-based batteries with high energy density. Dendritegrowth, volume change and high reactivity are the formidable challenges in terms of good cycling perfor-mance and high Coulombic efficiency as well as an expected safety guarantee of Na metal anode for thepractical application. Solid electrolyte interphase (SEI) layer as an indispensable component of a battery,its formation and stability play the critical role in the feasibility of Na metal anode. In this review, wefirst discuss the current consideration and challenges of Na metal anode, and then summarize severalstrategies to suppress dendrite growth and improve electrochemical performance, including interface en-gineering, electrolyte composition, electrode construction, and so on. Finally, the conclusion and futureperspective of potential development on Na metal anode are proposed.

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