Preparation of microsized crosslinked microspheres by dispersion copolymerization of polystyrene/polyethylene glycol 200-dimethacrylae

作     者：Wenli Guo Juan Wang Tongxiang Liang 

作者机构：Institute of Nuclear Energy Technology Tsinghua University Beijing 100084 China 

出 版 物：《Journal of University of Science and Technology Beijing》 (北京科技大学学报（英文版）)

年 卷 期：2006年第13卷第4期

页      面：380-384页

核心收录：

学科分类：08[工学] 0805[工学-材料科学与工程（可授工学、理学学位）] 080502[工学-材料学] 

主　　题：polystyrene microsphere dispersion polymerization crosslinking agent 

摘      要：Dispersion copolymerization of styrene with polyethylene glycol 200-dimethacrylae as the cross-linking agent was completed by using poly（N-vinyl pyrrolidone） and 2,2-azo-bisisobutyronitrile as the steric stabilizer and initiator, respectively. Crosslinked copolymeric microspheres were prepared directly by the one-step method of dispersion copolymerization. The effects of the content of polyethylene glycol 200-dimethacrylae on the particle morphology and the copolymerization rate were investigated. It shows that the crosslinking agent plays an important role in the particle morphology and the system stability. When the content of crosslinking reached 2.5wt%, the floriated particles were obtained.