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New design for highly durable infrared-reflective coatings

作     者:Chaoquan Hu Jian Liu Jianbo Wang Zhiqing Gu Chao Li Qian Li Yuankai Li Sam Zhang Chaobin Bi Xiaofeng Fan Weitao Zheng 

作者机构:State Key Laboratory of Superhard MaterialsKey Laboratory of Automobile Materials of MOEand School of Materials Science and EngineeringJilin UniversityChangchun 130012China School of ScienceChangchun University of Science and TechnologyChangchun 130022China Faculty of Materials and EnergySouthwest UniversityChongqing 400715China State Key Laboratory of Automotive Simulation and ControlJilin UniversityChangchun 130025China 

出 版 物:《Light(Science & Applications)》 (光(科学与应用)(英文版))

年 卷 期:2017年第6卷第1期

页      面:25-35页

核心收录:

学科分类:0808[工学-电气工程] 0809[工学-电子科学与技术(可授工学、理学学位)] 08[工学] 0805[工学-材料科学与工程(可授工学、理学学位)] 080502[工学-材料学] 0702[理学-物理学] 

基  金:the National Key R&D Program of China(2016YFA0200400) the National Natural Science Foundation of China(Grant No.51572104) the National Major Project for Research on Scientific Instruments of China(2012YQ24026404) the Program for JLU Science and Technology Innovative Research Team for financial support 

主  题:coating durability infrared reflectivity optical design 

摘      要:The fundamental challenge in designing durable infrared-reflective coatings is achieving the ideal combination of both high reflectivity and *** these competing demands is traditionally achieved by deposition of durable layers on highly reflective *** overturn the traditional logic of‘first reflectivity and then durability’and propose an alternative of‘first durability and then reflectivity’:First,a transition-metal compound is selected as a durable base;then its reflectivity is improved by incorporating silver/gold to form an alloy or by overcoating a multilayer *** validation experiments prove that the new strategy works extremely well:the coatings thus obtained have infrared reflectivities close to that of aluminum,and their hardness and acid and salt corrosion resistances are 27–50,400–1500 and 7500–25000 times that of *** traditional mirror coating(e.g.,Al/SiO2 films)is more suitable for moderate environments,while our mirror coating that was obtained by the new strategy(e.g.,an Ag-doped hafnium nitride film)is more suitable for harsh environments,such as ones with dust,windblown sand,moisture,acid rain or salt *** work opens up new opportunities for highly durable infrared-reflective coatings and rejuvenates the study of transition metal compounds in a completely new area of optics.

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