Comparison of the effect of carbon,halloysite and titania nanotubes on the mechanical and thermal properties of LDPE based nanocomposite films

作     者：Khaliq Majeed Mariam Al Ali AlMaadeed Moustafa M.Zagho 

作者机构：Center for Advanced MaterialsQatar UniversityPO Box 2713DohaQatar Department of Chemical EngineeringCOMSATS Institute olin formation TechnologyLahorePakistan Materials Science and Technology ProgramQatar UniversityPO Box 2713DohaQatar 

出 版 物：《Chinese Journal of Chemical Engineering》 (中国化学工程学报（英文版）)

年 卷 期：2018年第26卷第2期

页      面：428-435页

核心收录：

学科分类：0710[理学-生物学] 0830[工学-环境科学与工程（可授工学、理学、农学学位）] 07[理学] 0817[工学-化学工程与技术] 08[工学] 070205[理学-凝聚态物理] 080501[工学-材料物理与化学] 0805[工学-材料科学与工程（可授工学、理学学位）] 080502[工学-材料学] 0703[理学-化学] 0702[理学-物理学] 

基　　金：NPRP grant#(NPRP5-039-2-014)from the Qatar National Research Fund(a member of Qatar Foundation) 

主　　题：Hydrothermal Nanostructure Nanotube Nanocomposite Mechanical properties Thermal properties 

摘      要：In this study, titania nanotubes （TNTs） were prepared by hydrothermal method with the aim to compare the properties of these one-dimensional tubular nanostructures＇ reinforced nanocomposites with the carbon and halloysite nanotubes＇ （CNTs and HNTs, respectively） reinforced nanocomposites. Low density polyethylene （LDPE） was used as the matrix material. The prepared nanocomposites were characterized and compared by means of their morphological, mechanical and thermal properties. SEM results showed enhanced interracial interaction and better dispersion of TNTs and HNTs into LDPE with the incorporation of a MAPE compatibilizer, however, these interactions seem to be absent between CNTs and LDPE, and the CNTs remained agglomerated. Contact angle measurements revealed that CNT filled nanocomposites are more hydrophilic than HNT composites, and less than TNT composites. CNTs provided better tensile strength and Young＇s modulus than HNT and TNT nanocomposites, a 42% increase in tensile strength and Young＇s modulus is achieved compared to LDPE. Tear strength improvement was noticed in the TNT composites with a value of 35.4 N. mm -1, compared to CNT composites with a value of 25.5 *** 1 -s- 1. All the prepared nanocomposites are more thermally stable than neat LDPE and the best improvement in thermal stability was observed for CNT reinforced nanocomposites. CNTs depicted the best improvement in tensile and thermal properties and the MAPE compatibilizer effective- ness regarding morphological, mechanical and thermal properties was only observed for TNT and HNT systems.