Research progress in the SO2 resistance of the catalysts for selective catalytic reduction of NOx
Research progress in the SO_2 resistance of the catalysts for selective catalytic reduction of NO_x作者机构:Key Laboratory for Green Chemical Technology of Ministry of Education R&D Center for Petrochemical Technology Tianjin University Tianjin 300072 China Collaborative Innovation Center of Chemical Science and Engineering Tianjin 300072 China
出 版 物:《Chinese Journal of Chemical Engineering》 (中国化学工程学报(英文版))
年 卷 期:2017年第25卷第12期
页 面:1695-1705页
核心收录:
学科分类:081705[工学-工业催化] 08[工学] 0817[工学-化学工程与技术]
基 金:Supported by the Scientific Research Foundation for the Returned Overseas Chinese Scholars,State Education Ministry the National Natural Science Foundation of China(21506150)
主 题:Words Selective catalytic reduction (SCR)SO2 resistance catalyst NOx
摘 要:The selective catalytic reduction (SCR) of NOx with NH3 has been proven to be an efficient technology for NOx conversion to N2. However, the catalysts used for SCR usually suffer from the problem of sulfur poisoning which seriously limits their practical application. This review summarized sulfur poisoning mechanisms of various SCR deNG catalysts and strategies to reduce deactivation caused by SO2 such as doping metals, controlling the structures and morphologies of the catalysts, and selecting appropriate supports. The methods and procedures of catalysts preparation and the reaction conditions also have effect on SO2-resistance of the catalysts. Several novel catalyst systems that exhibited good SO2 resistance are also introduced. This paper could provide guidance for the development of highly efficient sulfur-tolerant deNOx catalysts.