固体催化剂是否成功地仿效酶催化剂？(英文)

作     者：Bernard DELMON 

作者机构：Université catholique de LouvainCATACatalysis and Chemistry of Disperse MaterialsPlace Croix du Sud 2/17B-1348 Louvain-la-NeuveBelgium 

出 版 物：《催化学报》 (CHINESE JOURNAL OF CATALYSIS)

年 卷 期：2010年第31卷第8期

页      面：859-871页

核心收录：

学科分类：081705[工学-工业催化] 08[工学] 0817[工学-化学工程与技术] 

主　　题：inorganic catalyst enzyme activity selectivity 

摘      要：In many aspects,similitude exists between man-made catalysts and *** scientific insight into this similitude stimulate new research directions in catalysis? More precisely,can the understanding of the mechanisms of activity control in enzymes suggest new advances for man-made catalysts? Indeed,it is already possible to design catalysts with (i) new structures (*** of several phases) and (ii) a better balance between the roles of the different *** ambition is to keep the essential advantages of solids as catalysts,in particular robustness,easy separation from products,and tolerance to high temperatures,while adding the advantages typical of enzymes,like more activity,allostery,and more precise control of selectivity,in particular *** ambition is to build a bridge between robust man-made functional solids and fragile but extremely selective *** that,results from a line of the work in our group will be used.