A N-tripodal Ligand Cu-Based Coordination Polymer with Good Catalytic Activity for the Reduction of 4-Nitrophenol

作     者：金矿 胡劲松 吕超南 刘俊 李盛雨 程婷婷 周春辉 何志伟 张明道 

作者机构：School of Chemical Engineering Anhui University of Science and Technology Jiangsu Key Laboratory of Atmospheric Environment Monitoring and Pollution Control (AEMPC) School of Environmental Sciences and Engineering Nanjing University of Information Science and Technology 

出 版 物：《Chinese Journal of Structural Chemistry》 (结构化学（英文）)

年 卷 期：2017年第36卷第8期

页      面：1361-1367页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070305[理学-高分子化学与物理] 080501[工学-材料物理与化学] 0805[工学-材料科学与工程（可授工学、理学学位）] 0703[理学-化学] 

基　　金：Supported by the National Natural Science foundation of China(21301005,21671004,51404006) Natural Science Foundation of Anhui Province(1408085QB31) the open fund of Jiangsu Key Laboratory of Atmospheric Environment Monitoring and Pollution Control(KFK201508) 

主　　题：coordination polymer catalysis reduction of nitrophenol 

摘      要：A complex {[Cu（tib）2（H2O）2]·（NO3）2}n（1） has been synthesized under N,N-dimethylacetamide（DMA） and water conditions. The structure of complex 1 was characterized by single-crystal X-ray crystallography. It crystallizes in monoclinic, space group P21/n with a = 10.6273（7）, b = 11.4184（7）, c = 13.4215（8） A, β = 108.290（2）°, V = 1546.38（17）A3, Z = 2, F（000） = 798, Dc = 1.667 g/cm3 and m = 0.786 mm-1） Complex 1 exhibits a 3D network due to the existence of O–H…O interaction between coordinated water and nitrate anions. Furthermore, complex 1 has a good catalytic activity for the reduction of 4-nitrophenol in Na BH4 solution.