Effect of metallic ions on dispersibility of fine diaspore

作     者：周瑜林 胡岳华 王毓华 ZHOU Yu-lin;HU Yue-hua;WANG Yu-hua

作者机构：中南大学资源加工与生物工程学院长沙410083 

出 版 物：《Transactions of Nonferrous Metals Society of China》 (中国有色金属学报（英文版）)

年 卷 期：2011年第21卷第5期

页      面：1166-1171页

核心收录：

学科分类：080603[工学-有色金属冶金] 08[工学] 0806[工学-冶金工程] 

基　　金：Project (2005CB623701) supported by the National Basic Research Program of China 

主　　题：diaspore metallic ions dispersibility zeta potential DLVO theory 

摘      要：Dispersion experiments were conducted to study the influence of metallic cations on the dispersibility of diaspore. The reaction mechanisms were investigated based on the analysis of zeta （ξ） potential and calculations of solution chemistry and DLVO theory. The results show that the valence of cations, instead of the cation type, plays an important role in the dispersibility of diaspore The impact of multivalent metallic cations is greater than that of monovalent cations. In the presence of Ca^2＋ and Mg^2＋, the dispersion of diaspore doesn＇t change in the range of pH value below 10. However, Ca^2＋ and Mg^2＋ may induce strong coagulation of particles when pH value is higher than 10. The adsorption of species of calcium and magnesium ions on diaspore can cause the compression of electric double layer, the decrease of the absolute value of zeta potential and the repulsion force between diaspore particles. The new IEP （isoelectric point） appeared at pH value of 11 may attribute to the adsorption of Mg（OH）2（s）.