Synthesis and Characterization of Tb-incorporated Apatite Nano-scale Powders

作     者：L.J. Sun P.F. Ni D.G. Guo C.Q. Fang J. Wang F. Yang X.F. Huang Y.Z. Hao H. Zhu K.W. Xu 

作者机构：State Key Laboratory for Mechanical Behavior of Materials School of Materials Science and Engineering Xi'an Jiaotong University Xi'an 710049 China School of Printing and Packaging Engineering Xi'an University of Technology Xi'an 710048 China Xi'an University of Arts and Science Xi'an 710065 China 

出 版 物：《Journal of Materials Science & Technology》 (材料科学技术（英文版）)

年 卷 期：2012年第28卷第9期

页      面：773-778页

核心收录：

学科分类：081702[工学-化学工艺] 08[工学] 0817[工学-化学工程与技术] 0805[工学-材料科学与工程（可授工学、理学学位）] 080502[工学-材料学] 

基　　金：supported by the Fundamental Research Funds for the Central University the National Natural Science Foundation of China (No. 51072159 51273159) Program for New Century Excellent Talents in Universities (Chinese Ministry of Education,NCET-08-0444) 

主　　题：Nano-scale powder Terbium (Tb) Wet chemical approach Apatite Biomedical materials 

摘      要：Nano-scale Tb-incorporated apatite （nano-Tb-AP） particles with different Tb contents （Tb/（Tb＋Ca）） of 0%, 5%, 10% and 20% were synthesized through a simple wet chemical method in this study. The crystal structure, thermal stabilities, chemical groups, crystal morphologies and crystal sizes of the nano--Tb-AP particles were characterized by X-ray diffraction （XRD）, Fourier transform infrared spectroscopy （FTIR）, and transmission electron microscopy （TEM）, respectively. It was found that lattice constants, particle sizes, crystalline and thermal stability varied with the doped Tb contents. With the increasing of Tb content, the lattice constants, particle size, length/diameter ratio, crystalline and thermal stability of nano-Tb-AP gradually decrease. Especially, almost all the 20%Tb-AP nano particles had been decomposed at 1200 ℃ while only a few of the decomposed products （β-TCP） were detected in the Tb-free nano apatite powders： This kind of nano-scale Tb-incorporated apatite exhibits an extremely potential clinic application because it integrates both the excellent biological functions of Tb element and apatite in human body.