SYNTHESIS AND CRYSTAL STRUCTURE OF THE Mo(O) TRINUCLEAR COMPLEXES: (Et_4N)_2[(CO)_4Mo(μ-S)_2-M(μ-S)_2Mo(CO)_4] (Ⅰ: M=Mo, Ⅱ: M=W)

作     者：萧泰 余佩华 庄伯涛 

作者机构：Department of Chemistry Northwest Normal University Lanzhou 730070 PRC Fujian Institute of Research on the Structure of Matter Academia Sinica Fuzhou 350002 PRC 

出 版 物：《Chinese Science Bulletin》 (科学通报(英文版))

年 卷 期：1992年第37卷第19期

页      面：1669-1670页

核心收录：

学科分类：07[理学] 08[工学] 

主　　题：valent complexes molybdenum CO Et₄N M=Mo M=W sulfur monoclinic specified 

摘      要：The complexes of lower valent molybdenum have special nature in the form of coordination and the changeability of valent state. In order to further investigate it, we synthesised the title compounds Ⅰ and Ⅱ which were trinuclear complexes containing M(O)and determined their crystal structure.