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Transcriptomics and physiological analyses reveal that sulfur alleviates mercury toxicity in rice(Oryza sativa L.)

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Journal of Environmental Sciences 2024年第1期135卷 10-25页

作者： Yingmei Huang Jicai Yi Xiaomin Li Fangbai Li National-Regional Joint Engineering Research Center for Soil Pollution Control and Remediation in South China Guangdong Key Laboratory of Integrated Agro-Environmental Pollution Control and ManagementInstitute of Eco-Environmental and Soil SciencesGuangdong Academy of SciencesGuangzhou 510650China Guangzhou Institute of Geochemistry Chinese Academy of SciencesGuangzhou 510640China University of Chinese Academy of Sciences Beijing 100049China College of Life Sciences South China Agricultural UniversityGuangzhou 510642China SCNU Environmental Research Institute Guangdong Provincial Key Laboratory of Chemical Pollution and Environmental Safety&MOE Key Laboratory of Theoretical Chemistry of EnvironmentSouth China Normal UniversityGuangzhou 510006China

Mercury(Hg)is one of the most dangerous contaminants and has sparked global concern since it poses a health risk to humans when consumed through rice.sulfur(S)is a crucial component for plant growth,and S may reduce Hg accumulation in rice grains.However,the detailed effects of S and the mechanisms underlying S-mediated responses in Hg-stressed rice plants remain unclear.Currently,to investigate the effects of S addition on rice growth,Hg accumulation,physiological indexes,and gene expression profiles,rice seedlings were hydroponically treated with Hg(20μmol/L Hg Cl_(2))and Hg plus elemental sulfur(100 mg/L).S application significantly reduced Hg accumulation in Hg-stressed rice roots and alleviated the inhibitory effects of Hg on rice growth.S addition significantly reduced Hg-induced reactive oxygen species generation,membrane lipid peroxidation levels,and activities of antioxidant enzymes while increasing glutathione content in leaves.Transcriptomic analysis of roots identified 3,411,2,730,and 581 differentially expressed genes in the control(CK)vs.Hg,CK vs.Hg+S,and Hg vs.Hg+S datasets,respectively.The pathway of S-mediated biological metabolism fell into six groups:biosynthesis and metabolism,expression regulation,transport,stimulus response,oxidation reduction,and cell wall biogenesis.The majority of biological process-related genes were upregulated under Hg stress compared with CK treatment,but downregulated in the Hg+S treatment.The results provide transcriptomic and physiological evidence that S may be critical for plant Hg stress resistance and will help to develop strategies for reduction or phytoremediation of Hg contamination.

关键词： sulfur Mercury Transcriptomics Detoxification

Arsenic and sulfur nanoparticle synthesis mimicking environmental conditions of submarine shallow-water hydrothermal vents

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Journal of Environmental Sciences 2022年第1期34卷 301-312页

作者： Vicente Durán-Toro Kurosch Rezwan Solveig I.Bühring Michael Maas MARUM–Center for Marine Environmental Sciences University of BremenBremen 28359Germany Advanced Ceramics University of BremenBremen 28359Germany MAPEX-Center for Materials and Processes University of BremenBremen 28359Germany

Arsenic and sulfur mineralization is a natural phenomenon occurring in hydrothermal systems where parameters like temperature and organic matter(OM)can influence the mobilization of the toxic metalloid in marine environments.In the present study we analyze the influence of temperature and OM(particularly sulfur-containing additives)on As and S precipitation based on the recent discovery of As-rich nanoparticles in the hydrothermal system near the coast of the Greek island Milos.To this end,we experimentally recreate the formation of amorphous colloidal particles rich in As and S via acidification(pH 3–4)of aqueous precursors at various temperatures.At higher temperatures,we observe the formation of monodisperse particles within the first 24 h of the experiment,generating colloidal particles with diameters close to 160 nm.The S:As ratio and particle size of the synthetized particles closely correlates with values for As_(x)S_(y)particles detected in the hydrothermal system off Milos.Furthermore,organic sulfur containing additives(cysteine and glutathione,GSH)are a key factor in the process of nucleation and growth of amorphous colloidal As_(x)S_(y)particles and,together with the temperature gradient present in shallow hydrothermal vents,dictate the stabilization of As-bearing nanomaterials in the environment.Based on these findings,we present a simple model that summarizes our new insights into the formation and mobility of colloidal As in aquatic ecosystems.In this context,amorphous As_(x)S_(y)particles can present harmful effects to micro-and macro-biota not foreseen in bulk As material.

关键词： Biomineralization Milos Hydrothermal vent Arsenic sulfur Nanoparticles Ecotoxicology

The risks of sulfur addition on cadmium accumulation in paddy rice under different water-management conditions

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Journal of Environmental Sciences 2022年第8期34卷 101-111页

作者： Zhe Liu Qi-qi Wang Si-yu Huang Ling-xuan Kong Zhong Zhuang Qi Wang Hua-fen Li Ya-nan Wan Beijing Key Laboratory of Farmland Soil Pollution Prevention and Remediation Key Laboratory of Plant-Soil Interactions of the Ministry of EducationCollege of Resources and Environmental SciencesChina Agricultural UniversityBeijing 100193China

Recently, the application of sulfur(S) has been recommended to control the accumulation of cadmium(Cd) in rice in contaminated paddy soil. However, the effects of exogenous S on Cd transfer in paddy rice systems under different water-management practices have not been systematically investigated. Pot experiments were performed to monitor the composition of soil pore water and the Cd accumulation in iron plaque and rice tissue were compared under different S(0 and 200 mg/kg Na_(2)SO_(4)) and water(continuous and discontinuous flooding) treatments. sulfur application significantly increased Cd concentrations in soil pore water under discontinuous flooding conditions, but slightly reduced them under continuous flooding. Moreover, the oxidation/reduction potential(Eh) was the most critical factor that affected the Cd levels. When the Eh exceeded-42.5 mV, S became the second critical factor, and excessive S application promoted Cd dissolution. In addition, S addition elevated the Cd levels in iron plaque and reduced the Cd transfer from the iron plaque to rice roots. In rice, S addition inhibited Cd transfer from the rice roots to the straw;thus, more Cd was stored in the rice roots. Nevertheless, additional S application increased the Cd content in the rice grains by 72% under discontinuous flooding, although this effect was mitigated by continued flooding. Under simulated practical water management conditions, S addition increased the risk of Cd contamination in rice, suggesting that S application should be reconsidered as a paddy fertilization strategy.

关键词： Rice Cadmium sulfur Water management Iron plaque Accumulation

Functional Hyperbranched Polythioamides Synthesized from Catalyst-free Multicomponent Polymerization of Elemental sulfur

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Chinese Journal of Chemistry 2022年第6期40卷 725-733页

作者： Shangrun Liu Fengting Li Wenxia Cao Rongrong Hu Ben Zhong Tang State Key Laboratory of Luminescent Materials and Devices Guangdong Provincial Key Laboratory of Luminescence from Molecular AggregatesSouth China University of TechnologyGuangzhouGuangdong 510640China Shenzhen Institute of Molecular Aggregate Science and Engineering School of Science and EngineeringThe Chinese University of Hong KongShenzhen CityGuangdong 518172China AIE Institute GuangzhouGuangdong 510530China Hong Kong Branch of Chinese National Engineering Research Center for Tissue Restoration and Reconstruction The Hong Kong University of Science&TechnologyClear Water BayKowloonHong KongChina

Hyperbranched polymers with unique topological structures,large number of branching sites and terminal groups have attracted much attention,and are expected to possess advanced functionalities compared with their linear polymer counterparts.The devel-opment of hyperbranched polymers is hence highly desired but challenging,especially for sulfur-containing polymers which are at-tractive metal absorbents,optical materials,dielectric materials,and self-healing materials.In this work,six hyperbranched polythi-oamides with various topological structures,well-defined repeating units,satisfying yields(up to 99%),and high molecular weights(up to 101400 g/mol)were successfully designed and synthesized from the catalyst-free multicomponent polymerization of ele-mental sulfur,aromatic alkynes and aliphatic amines,through different monomer combination strategies based on the designed three-or four-functional alkyne and amine monomers.The hyperbranched polythioamides possess unique luminescence property,and strong affinity toward Hg^(2+),which can be utilized in the fluorescence detection of Hg^(2+),as well as mercury removal from aque-ous solutions with high efficiency of 99.99%and low mercury residue of 0.1 ppb.Hyperbranched polythioamides with unique struc-tures may be developed to a group of fascinating materials and find their potential applications as metal absorbents and optoelec-tronic materials.

关键词： Hyperbranched polymer Polythioamide Polymerization sulfur Mercury

Promotion effect of sulfur impurity in alumina support on propane dehydrogenation

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Journal of Energy Chemistry 2022年第7期31卷 332-339,I0009页

作者： Xin-Qian Gao Wen-Cui Li Bin Qiu Jian Sheng Fan Wu An-Hui Lu State Key Laboratory of Fine Chemicals School of Chemical EngineeringDalian University of TechnologyDalian 116024LiaoningChina

Alumina materials are widely applied either as a catalyst or support in various industrial catalytic processes. Impurities in alumina that are unfriendly to catalytic performance are inevitably present during the production processes. Facing this problem, we here report that the use of sulfur-containing alumina as the support can generate active alumina-supported platinum catalyst, which exhibits superior propylene selectivity and anti-coking ability during propane dehydrogenation. It demonstrated that the sulfur impurity in alumina is not entirely detrimental. During the reduction process, the formation of gas-phase sulfur species increased the electrons and poisoned unsaturated sites of platinum particles. The sulfur impurity in alumina can be removed through a hydrogen reduction process, and the degree of desulfurization is correlated with the operating temperature. This study demonstrated that the rational use of impurity will contribute to the design of a catalyst with high reactivity for potential applications.

关键词： Alumina Impurity sulfur Platinum Propane dehydrogenation

Pt-confinement catalyst with dendritic hierarchical pores on excellent sulfur-resistance for hydrodesulfurization of dibenzothiophene and 4,6-dimethyldibenzothiophene

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Green Energy & Environment 2022年第2期7卷 324-333页

作者： Xilong Wang Chengkun Xiao Mohnnad H.Alabsi Peng Zheng Zhengkai Cao Jinlin Mei Yu Shi Aijun Duan Daowei Gao Kuo-Wei Huang Chunming Xu State Key Laboratory of Heavy Oil Processing China University of Petroleum(Beijing)Beijing102249China KAUST Catalysis Center and Division of Physical Sciences and Engineering King Abdullah University of Science and TechnologyThuwal23955-6900Saudi Arabia School of Chemistry and Chemical Engineering University of JinanJinan250022China

Metal confinement catalyst Mo S_(2)/Pt@TD-6%Ti(TD,TS-1/Dendritic mesoporous silica nanoparticles composite) in dendritic hierarchical pore structures was synthesized and showed excellent sulfur-resistance performance and stabilities in catalytic hydrodesulfurization reactions of probe sulfide molecules.The Mo S_(2)/Pt@TD-6%Ti catalyst combines the concepts of Pt-confinement effect and hydrogen spillover of Pt noble metal.The modified micropores of Mo/Pt@TD-6%Ti only allow the migration and dissociation of small H_(2) molecules(0.289 nm),and effectively keep the sulfur-containing compounds(e.g.H_(2)S,0.362 nm) outside.Thus,the Mo S_(2)/Pt@TD-6%Ti catalyst exhibits higher DBT and 4,6-DMDBT HDS activities because of the synergistic effect of the strong H_(2) dissociation ability of Pt and desulfurization ability of Mo S_(2) with a lower catalyst cost.This new concept combining H2dissociation performance of noble metal catalyst with the desulfurization ability of transition metal sulfide Mo S_(2) can protect the noble metal catalyst avoiding deactivation and poison,and finally guarantee the higher activities for DBT and 4,6-DMDBT HDS.

关键词： catalyst sulfur pores

Structural screening of phosphorus sulfur ternary hydride PSH_(6) with a high-temperature superconductivity at 130 GPa

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Frontiers of physics 2023年第2期18卷 205-211页

作者： Yu-Long Hai He-Jin Yan Yong-Qing Cai Joint Key Laboratory of the Ministry of Education Institute of Applied Physics and Materials EngineeringUniversity of MacaoTaipaMacaoChina

In our study,we constructed a series of inorganic nonmetallic ternary hydrides PSH6 by first-principles structural screening under pressure of 200 GPa.The structural stability under lower pressure are examined.Focusing on the structural stability,electronic and phonon properties,as well as the possible superconducting properties within the framework of Bardeen−Cooper−Schrieffer(BCS)theory,we show that PSH6 with space group possesses a superconducting transition temperature of 146 K at 130 GPa.In the pressure range of 100−200 GPa,our work suggests that the ternary phosphorus-sulfur-hydrogen would act as a promising compositional and elemental space for achieving high-temperature superconductivity.

关键词： phosphoruses sulfur hydrides high-temperature superconductivity low-pressure structural screening

Raman spectroscopy based detection of corrosive sulfur in transformer oil:Method and application

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High Voltage 2022年第6期7卷 1175-1184页

作者： Ziyi Wang Ruimin Song Weigen Chen Xinyuan Zhang Pinyi Wang State Key Laboratory of Power Transmission Equipment&System Security and New Technology Chongqing UniversityChongqingChina

In order to overcome the shortcomings of traditional methods for corrosive sulfur detection in transformer oil,Raman spectroscopy based detection is proposed in this paper.The widely concerned corrosive sulfur,Dibenzyl Disulfide(DBDS),was chosen as the characteristic molecule to be detected.A series of oil samples with different DBDS concentrations was prepared.And these samples were extracted by 1-methyl-2-pyrrolidinone for DBDS enrichment to improve the sensitivity of detection.Then Raman spectra of samples were obtained,and a linear model was established by analysing the relationship between the characteristic peak and the DBDS concentration.The limit of detection reached 7.98 mg/kg.For determining the DBDS concentrations causing sulfur corrosion,the sulfur weight content on the copper conductor surface was measured by Scanning Electron Microscope-Energy Dispersive Spectrometer after a corrosion test.The results show that the corrosion limitation highly depends on the type of transformer oil,and the Raman spectroscopy detection can meet the limit of detection requirement in practical condition.Finally,an on-site oil sample and five Lab-made samples were detected via our new method and the current Gas Chromatography-Mass Spectrometry based method.It is found that there is no significant divergence between the measurement results.And good applicability was also demonstrated in onsite sample test.

关键词： corrosion sulfur spectroscopy

sulfur-encapsulated in heteroatom-doped hierarchical porous carbon derived from goat hair for high performance lithium–sulfur batteries

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Journal of Energy Chemistry 2019年第3期28卷 121-131页

作者： Juan Ren Yibei Zhou Huali Wu Fengyu Xie Chenggang Xu Dunmin Lin College of Chemistry and Materials Science Sichuan Normal University

Biomass-derived carbon materials have aroused widespread concern as host material of sulfur to enhance electrochemical performances for lithium–sulfur batteries. Herein, goat hair, as a low-cost and eco-friendly precursor, is employed to fabricate cauliflower-like in-situ nitrogen, oxygen and phosphorus tri-doped porous biomass carbon(NOPC) by a facile activation with H_3PO_4 and carbonization process.The morphology and microstructure of NOPC can be readily tuned by altering pyrolysis temperature. The as-prepared NOPC matrix material carbonized at 600 °C possesses 3D hierarchical porous structure, high specific surface area(535.352 m^2 g^(-1)), and appropriate pore size and pore size distribution. Encapsulating sulfur into the NOPC depends on a stem-melting technology as cathode materials of Li–S batteries. Due to the synergistic effect of special physical structure and inherent tri-doping of N, O and P, electrons and ions transfer and utilization of active sulfur in the materials are improved, and the shuttle behaviors of soluble lithium polysulfides are also mitigated. Consequently, the S/NOPC-600 composite exhibits excellent electrochemical performance, giving a high initial discharge capacity of 1185 mA h g^(-1) at 0.05 C and maintaining a relatively considerable capacity of 489 m A h g^(-1) at 0.2 C after 300 cycles. Our work shows that a promising candidate for cathode material of Li–S batteries can be synthesized using low-cost and renewable biomass materials by a facile process.

关键词： Biomass-derived carbon materials Goat hair Nitrogen Oxygen and phosphorus tri-doping Lithium sulfur batteries