A new method for introduction ω-side chain of prostanoid using Barton radical reaction
A new method for introduction ω-side chain of prostanoid using Barton radical reaction作者机构:Institute of Materia Medica Peking Union Medical College Chinese Academy Medical Sciences Beijing 100050 China
出 版 物:《Chinese Chemical Letters》 (中国化学快报(英文版))
年 卷 期:2009年第20卷第3期
页 面:253-255页
核心收录:
学科分类:081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 0905[农学-畜牧学] 070305[理学-高分子化学与物理] 09[农学] 080501[工学-材料物理与化学] 0805[工学-材料科学与工程(可授工学、理学学位)] 0703[理学-化学] 090501[农学-动物遗传育种与繁殖]
基 金:the Ministry of Health for the financial support of China(No.94-2-025)
主 题:Acid chloride N-Hydroxy-2-thiopyridine Barton ester ω-Side chain of prostanoid
摘 要:A new method for introduction to-side chain of prostanoid was described in this note. Starting from acid chloride (3), via Barton radical reaction, a trans α,β-unsaturated ketone sython was introduced.