Preparation and near-infrared optical limiting property of fluorene-containing functional polyacetylene

作     者：Nai Bo Lin Yan Feng Shan Yi Guang Hong Yao Xu 

作者机构：College of Material Science and Engineering ＆ College of Chemistry and Chemical Engineering Donghua University Shanghai 201620 China College of Chemistry and Chemical Engineering Anhui University Hefei 230039 China 

出 版 物：《Chinese Chemical Letters》 (中国化学快报（英文版）)

年 卷 期：2011年第22卷第10期

页      面：1257-1260页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070305[理学-高分子化学与物理] 080501[工学-材料物理与化学] 0805[工学-材料科学与工程（可授工学、理学学位）] 080502[工学-材料学] 0703[理学-化学] 

基　　金：financially supported by the National Natural Science Fund of China(Nos.20971021,51073031 and 20974018) the National Oversea Scholar Cooperation Research Found of China(No.50928301) 

主　　题：Substituted polyacetylene Fluorene Nonlinear optics Two-photon absorption 

摘      要：A novel functional polyacetylene containing fluorene group as a pendant,poly（2-（p-methylstyrene）-7-acetylene-9,9-dioctyl-fluorene）, was synthesized in moderate yield by[Rh（nbd）Cl]_2-Et_3N *** structures and properties of monomer and polymer were characterized and evaluated with FTIR,NMR,UV-vis,GPC and Z-scan,*** results show that the incorporation of fluorene into polyacetylene has endowed the resultant polymer with well optical limiting properties for laser at wavelength 780 nm based on two-photon absorption mechanism.