Effects of electrolyte components on properties of Al alloy anode
Effects of electrolyte components on properties of Al alloy anode作者机构:School of Materials Science and Engineering Central South University
出 版 物:《中国有色金属学会会刊:英文版》 (Transactions of Nonferrous Metals Society of China)
年 卷 期:2009年第19卷第1期
页 面:160-165页
核心收录:
学科分类:0806[工学-冶金工程] 08[工学] 0818[工学-地质资源与地质工程] 0815[工学-水利工程] 0805[工学-材料科学与工程(可授工学、理学学位)] 080502[工学-材料学] 0703[理学-化学] 0813[工学-建筑学] 0814[工学-土木工程] 0702[理学-物理学]
摘 要:The effects of Na2SnO3, In(OH)3 and Na2SnO3+In(OH)3 on the properties of Al alloy anode were studied in alkaline medium at 25 ℃. The self-corrosion rate of Al alloy anode was studied by method of H2 immersed in aqueous medium, and the electrochemical properties of Al alloy anode were tested via galvanostatic discharge and dynamic potential methods. The results show that the self-corrosion rate of Al alloy anode in 4 mol/L NaOH+3 mol/L NaAlO2 medium can be minimized by adding Na2SnO3, In(OH)3 and Na2SnO3+ In(OH)3. Na2SnO3, In(OH)3 and Na2SnO3+In(OH)3 make Al anodic potential shift positively in galvanostatic discharging. The most effective additive of Al alloy anode in 4 mol/L NaOH+3 mol/L NaAlO2 medium is 0.075 mol/L Na2SnO3+0.005 mol/L In(OH)3, integrating self-corrosion rate and electrochemical properties.